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Debenzylation by Ni-A1 alloy

Naidu, MV and Rao, GSK (1980) Debenzylation by Ni-A1 alloy. In: Journal of the Indian Institute of Science, 62 (10). pp. 177-180.

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Abstract

Nickel-aluminum alloy in aqueous sodium hydroxide-ethanol medium brings about facile hydro-enolrsis of benzyl ether function in substrates carrying a vicinal methoxy group. Simplicity of the reaction conditions and cheapness of the reagent are some of the advanrages of the procedure. Additionally, carbonyl functions when present are untouched and alkaline medium of the reaction makes it compatible with the presence of acid-sensitite groups.

Item Type: Editorials/Short Communications
Additional Information: Copyright of this article belongs to J Indian Institute of science.
Keywords: Ni-A1 alloy, benzyl ether cleavage, hydrogenolyw, debenzylalion.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 28 Dec 2010 06:48
Last Modified: 28 Dec 2010 06:48
URI: http://eprints.iisc.ernet.in/id/eprint/34629

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