Meenakumari, Shanmugam and Chakravarty, Akhil R (1992) Three different co-ordination geometries in the pentacopper(II) unit of [Cu5(OH)2(H2O)(O2CMe)6(Him)4][ClO4]2(Him = imidazole). In: Dalton Transactions (14). pp. 2305-2306.
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The reaction of imidazole (Him) with [Cu2(µ-O2CMe)4(H2O)2] in water–NaClO4 led to the formation of a polynuclear copper(II) complex, [Cu5(OH)2(H2O)(O2CMe)6(Him)4][ClO4]21, in which the pentanuclear units, showing four, five and six co-ordination geometries for the copper(II) centres and Cu Cu distances of 3.043(1), 3.178(1) and 3.578(1)Å, were linked by aqua bridges to give an intra-chain inter-unit Cu Cu separation of 4.507(1)Å.
|Item Type:||Editorials/Short Communications|
|Additional Information:||Copyright of this article belongs to Royal Society of Chemistry.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||04 Jan 2011 08:48|
|Last Modified:||04 Jan 2011 08:48|
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