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Electron energy loss spectroscopic study of Cr(CO)6, Mo(CO)6 and W(CO)6 in the vapour phase

Pradeep, T (1990) Electron energy loss spectroscopic study of Cr(CO)6, Mo(CO)6 and W(CO)6 in the vapour phase. In: Proceedings of the Indian Academy of Sciences - Chemical Sciences, 102 (1). pp. 1-5.

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Abstract

Electron energy loss spectra (EELS) of Cr, Mo and W hexacarbonyls in the vapour phase are reported. Most of the bands observed are similar to those in optical spectra, but the two high energy transitions in the 9·8–11·2 eV region are reported here for the first time. Based on the orbital energies from the ultraviolet photoelectron spectra and the electronic transition energies from EELS and earlier optical studies, the molecular energy level schemes of these molecules are constructed.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Keywords: Electron energy loss spectra;transition metal hexacarbonyls; molecular energy level schemes.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 11 Feb 2011 06:50
Last Modified: 11 Feb 2011 06:50
URI: http://eprints.iisc.ernet.in/id/eprint/35126

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