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Dynamics of activationless reactions in solution

Bagchi, Biman and Fleming, Graham R (1990) Dynamics of activationless reactions in solution. In: Journal of Physical Chemistry, 94 (1). pp. 9-20.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/j100364a004

Abstract

Recent picosecond and subpicosecond laser spectroscopy experiments have revealed several chemically and biologically important reactions in solution in which the reaction potential surface does not present a barrier to the motion along the reaction coordinate.The dynamics of these reactions display diverse and interesting behavior. They include the dependence of relaxation rate on the solvent viscosity, the solvent polarity, the temperature, and the wavelength of the exciting light. In this article we review the recent developments in the theoretical description of activationless processes in solution and compare them with the available experimental results

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 03 Feb 2011 12:14
Last Modified: 03 Feb 2011 12:14
URI: http://eprints.iisc.ernet.in/id/eprint/35174

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