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Acid-Catalyzed Thermal Rearrangement of Gamm,Delta-Unsaturated Ketones

Srikrishna, A and Krishnan, KS and Vankateswarlu, S (1993) Acid-Catalyzed Thermal Rearrangement of Gamm,Delta-Unsaturated Ketones. In: Journal of the Chemical Society - Series Chemical Communications (2). 143-145 .

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Abstract

Thermal activation of gamma,delta-unsaturated ketones (1, 9 and 12) in the presence of a catalytic amount of propionic acid causes a rearrangement to give new gamma,delta-unsaturated ketones (2, 10 and 14) via an intramolecular ene reaction followed by a retro-ene reaction.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 31 Jan 2011 07:42
Last Modified: 31 Jan 2011 07:42
URI: http://eprints.iisc.ernet.in/id/eprint/35266

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