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(2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hydroxyperhydronaphthalene-2,3,6,7-te trayl tetraacetate

Mehta, Goverdhan and Sen, Saikat (2010) (2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hydroxyperhydronaphthalene-2,3,6,7-te trayl tetraacetate. In: Acta Crystallographica Section E, 66 (Part 1). O3095-U2472.

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Official URL: http://scripts.iucr.org/cgi-bin/paper?S16005368100...

Abstract

The title compound, C18H25FO9, exhibits a similar unit cell and packing to the alpha polymorph of axial 4a,8a-dihydroxyperhydronaphthalene-2,3,6,7-tetrayl tetraacetate. The carbonyl O atoms of two of the four acetate groups in the molecule are disordered over two sites with occupancy ratios of 0.59 (4):0.41 (4) and 0.57 (6):0.43 (6). Crystal packing is effected via intermolecular O-H center dot center dot center dot O hydrogen bonds, which link the tetraacetate molecules into tapes along the c axis.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to International Union of Crystallography.
Keywords: Single-crystal X-ray study; T = 291 K; mean (C–C) = 0.008 A° ;disorder in main residue; R factor = 0.043; wR factor = 0.167; data-to-parameter ratio = 7.1.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 31 Jan 2011 11:28
Last Modified: 31 Jan 2011 11:28
URI: http://eprints.iisc.ernet.in/id/eprint/35311

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