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Unusual isolation of a hemiaminal product from 4-cyclohexyl-3-thiosemicarbazide and di-2-pyridyl ketone: Structural and spectral investigations

Suni, V and Kurup, Prathapachandra MR and Nethaji, Munirathinam (2005) Unusual isolation of a hemiaminal product from 4-cyclohexyl-3-thiosemicarbazide and di-2-pyridyl ketone: Structural and spectral investigations. In: Journal of Molecular Structure, 749 (1-3). pp. 177-182.

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Abstract

Stable hemiaminal product was isolated as single crystals from the condensation reaction of di-2-pyridyl ketone with 4-cyclohexyl-3-thiosemicarbazide and structurally and spectrochemically characterized. The compound is the first report of a stable hemiaminal product of the condensation reaction of a substituted thiosemicarbazone. Spectral characterization was carried out using IR,UV-vis., $^{1}H NMR$, $^{13}C NMR$, COSY and HMQC. The compound crystallizes into a triclinic lattice with space group P-1. The molecule reveals a highly strained ZE conformation and a one-dimensional packing is effected by a network of intermolecular hydrogen bonding interactions in the unit cell.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier.
Keywords: Di-2-pyridyl ketone;Thiosemicarbazone;Hemiaminal;COSY;HMQC;Crystal structure
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 22 Aug 2005
Last Modified: 19 Sep 2010 04:19
URI: http://eprints.iisc.ernet.in/id/eprint/3532

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