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Interaction of C60 and C70 with aromatic amines in the ground and excited states. Evindence for fullerene—benzene interaction in the ground state

Seshadri, Ram and Rao, CNR and Pal, H and Mukherjee, T and Mittal, JP (1993) Interaction of C60 and C70 with aromatic amines in the ground and excited states. Evindence for fullerene—benzene interaction in the ground state. In: Chemical Physics Letters, 205 (4-5). pp. 395-398.

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Official URL: http://dx.doi.org/10.1016/0009-2614(93)87140-X

Abstract

While C60 interacts with aromatic amines such as dimethylaniline in the ground state, C70 does not. Fluorescence spectroscopic studies, including lifetime measurements, show the formation of exciplexes of both C60 and C70 with aromatic amines in nonaromatic solvents such as methylcyclohexane. Exciplexes are however not formed in benzene solvent, due to π—π interaction between benzene and the fullerene. Based on spectroscopic absorption measurements, it is shown that both C60 and C70 do indeed interact with benzene in the ground state.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Others
Date Deposited: 10 Feb 2011 10:15
Last Modified: 10 Feb 2011 10:15
URI: http://eprints.iisc.ernet.in/id/eprint/35510

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