ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Palladium(II) chloride complexes of bis(pyrazolyl)cyclotriphosphazenes

Chandrasekaran, A and Krishnamurthy, Setharampattu S and Nethaji, Munirathinam (1993) Palladium(II) chloride complexes of bis(pyrazolyl)cyclotriphosphazenes. In: Inorganic Chemistry, 32 (26). pp. 6102-6106.

[img] PDF
Palladium.pdf - Published Version
Restricted to Registered users only

Download (507Kb) | Request a copy
Official URL: http://pubs.acs.org/doi/abs/10.1021/ic00078a031

Abstract

Reactions of the bis(3,5-dimethylpyrazolyl)cyclotriphosphazene derivatives gem-N3P3(MeNCH(2)CH(2)O)(2)(dmp)(2) (1) and nongeminal cis-N3P3(OPh)(4)(dmp)(2) (2) with PdCl2 afford complexes of the type [PdCl2.(L)] (L = 1 or 2). In these complexes, the phosphazenes act as bidentate NN-donor ligands with the two pyrazolyl pyridinic nitrogen atoms bonded to the metal, thus forming a six- and an eight-membered chelate ring, respectively. The structures of 2 and [PdCl2.(2)] (4) have been confirmed by single-crystal X-ray diffraction. Crystal data for 2: a = 16.759(2) Angstrom, b = 10.788(3) Angstrom, c = 19.635(9) Angstrom, beta = 101.61(3)degrees, P2(1/c), Z = 4, R = 0.038 for 4688 reflections with F > 5 sigma(F). Crystal data for 4: a = 9.701(3) Angstrom, b = 24.853(4) Angstrom, c = 15.794(4) Angstrom, beta = 101.46(2)degrees, P2(1/n), Z = 4, R = 0.030 for 5416 reflections with F > 5 sigma(F).

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 18 Feb 2011 07:09
Last Modified: 18 Feb 2011 07:09
URI: http://eprints.iisc.ernet.in/id/eprint/35661

Actions (login required)

View Item View Item