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Raman spectral studies of borate glasses

Meera, BN and Ramakrishna , J (1993) Raman spectral studies of borate glasses. In: Journal of Non-Crystalline Solids, 159 (1-2). pp. 1-21.

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Official URL: http://dx.doi.org/10.1016/0022-3093(93)91277-A

Abstract

Raman spectroscopic measurements in borate glasses have been reviewe. The review shows that the technique is useful in identifying the structural groups present in the borate on the basis of the Krogh-Moe hypothesis. Vitreous B2O3 and alkali borates are extensvvely studied and a satisfactory assignment of bands is possible by a careful consideration of the literature. A cation effect on the borate netwoork is observed. Availaable measurements on binary borates other than alkali borates and on ternary borates are limited and more work is required to identify the structural modifications that take place with composition. Mixed alkali effect is reported only lithium-caesium borade and shows the formation of non-bridging oxygens, destroying the six-membered rings when Li2O is replaced by Cs2O. Fast ionic glasses (alkali borates containing alkali halides) yield the same Raman spectra as the alkali borates, except when the alkali is a fluoride.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 24 Feb 2011 05:03
Last Modified: 24 Feb 2011 05:03
URI: http://eprints.iisc.ernet.in/id/eprint/35720

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