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Chain Transfer of Alcohols in the Polymerization of Acrylic Esters

Nandi, US and Singh, M (1982) Chain Transfer of Alcohols in the Polymerization of Acrylic Esters. In: Die Makromolekulare Chemie, 183 . pp. 1467-1472.

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Abstract

Transfer constants were determined from the thermal polymerization of methyl, ethyl, and butyl acrylates for methyl, ethyl, propyl, and isopropyl alcohols at 80 C, utilising mixed-solvent systems wherever necessary. It was observed that the chain transfer constant for alcohols is not much affected by lengthening of the ester group in the acrylates, and the reactivity of the solvent is enhanced by an increased substitution at the \alpha-carbon atom in the alkyl group.

Item Type: Journal Article
Additional Information: The copyright belongs to Huthig & Wepf Verlag, Base
Keywords: polymerization;methyl acrylates;ethyl acrylates;butyl acrylates;mixedsolvent
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 01 Sep 2005
Last Modified: 19 Sep 2010 04:19
URI: http://eprints.iisc.ernet.in/id/eprint/3584

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