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Synthesis Based on Cyclohexadienes .11. A A new total synthesis of (±)-norprezizanone

Selvakumar, Natesan and Rao, Subba GSR (1993) Synthesis Based on Cyclohexadienes .11. A A new total synthesis of (±)-norprezizanone. In: Tetrahedron Letters, 34 (48). 7789-7792 .

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Official URL: http://dx.doi.org/10.1016/S0040-4039(00)61567-8

Abstract

Acid catalyzed rearrangement of endo 1-methoxytricyclo[6.2.2.0(3,8)]dodec-2-en-10-ol 8c afforded the ketone 9 which has been transformed into (+/-)-norprezizanone 19 thus completing a formal synthesis of (+/-)-zizaene. A key step in this strategy is a stereospecific 1,4-addition of a methyl group

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Cyloaddition; stereospecific 1,4-addition; sesquiterpene synthesis
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 11 Mar 2011 06:38
Last Modified: 11 Mar 2011 06:38
URI: http://eprints.iisc.ernet.in/id/eprint/35857

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