Vijayasankar, AV and Deepa, S and Venugopal, BR and Nagaraju, N (2010) Amorphous Mesoporous Iron Aluminophosphate Catalyst for the Synthesis of 1,5-Benzodiazepines. In: Chinese Journal of Catalysis, 31 (11). pp. 1321-1327.
![[img]](http://eprints.iisc.ernet.in/style/images/fileicons/application_pdf.png) |
PDF
Amor.pdf - Published Version Restricted to Registered users only Download (225Kb) | Request a copy |
Abstract
A simple and versatile method for the synthesis of 1,5-benzodiazepines from o-phenylenediamine and ketones in the presence of solvents and under solvent-free conditions that used an amorphous mesoporous iron aluminophosphate as catalyst was developed. High yields with excellent selectivity were obtained with a wide variety of ketones under mild reaction conditions. The catalyst had the advantages of ease of preparation, ease of handling, simple recovery, reusability, non toxicity, and being inexpensive.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | benzodiazepine; amorphous metal aluminophosphate; mesoporous iron aluminophosphate; o-phenylenediamine; ketone; solvent free synthesis |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 08 Mar 2011 06:42 |
| Last Modified: | 08 Mar 2011 06:42 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/35906 |
Actions (login required)
 |
View Item |
