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A β,β,β-trialkoxyethyllithium stable towards fragmentation: a carboxyl protected acetic acid dianion equivalent

Chandrasekhar, S and Roy, CD (1944) A β,β,β-trialkoxyethyllithium stable towards fragmentation: a carboxyl protected acetic acid dianion equivalent. In: Tetrahedron, 50 (27). 8099 -8102.

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Official URL: http://dx.doi.org/10.1016/S0040-4020(01)85292-3

Abstract

The novel alkyllithium 1b is not only intriguingly stable towards fragmentation, but also a synthetically useful reagent, complementing current carboxylic ester enolate methodology. Its design is based on interesting mechanistic principles, and harnesses the known stability of the 2,4,10-trioxaadamantane framework.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 03 Jun 2011 08:00
Last Modified: 03 Jun 2011 08:00
URI: http://eprints.iisc.ernet.in/id/eprint/36092

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