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A study of the reaction of divalent transition metal chlorides with pyridinium poly(hydrogen fluoride), ppht, and the effect of potassium hydrogen fluoride on fluorination and complexation

Singh, RN and Padma, DK (1994) A study of the reaction of divalent transition metal chlorides with pyridinium poly(hydrogen fluoride), ppht, and the effect of potassium hydrogen fluoride on fluorination and complexation. In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 24 (5). 779 -790.

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Abstract

Studies of the reaction of metal chlorides, MCl2 (M = Mn, Co, Ni, Cu, Zn) with PPHF at room temperature have shown that Mn, Co and Zn form the corresponding metal fluorides, MF2, while Ni and Cu form their dipyridine metal(II) dichloride complexes. Nickel and copper complexes further undergo fluorination and complexation by potassium hydrogen fluoride in PPHF to form KNiF3 and KCuF3.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Taylor and francis group.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 26 Mar 2011 06:00
Last Modified: 26 Mar 2011 06:00
URI: http://eprints.iisc.ernet.in/id/eprint/36253

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