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Chiral Synthons from Carvone. Part 10. Synthesis of (+)-(1S,3S,4S,7S, 8R)-5,7-Dimethyl-10-oxatetracyclo-(5.3.0.03,5,04,8)decan-9-one.

Srikrishna, A and Sharma, GVR (1994) Chiral Synthons from Carvone. Part 10. Synthesis of (+)-(1S,3S,4S,7S, 8R)-5,7-Dimethyl-10-oxatetracyclo-(5.3.0.03,5,04,8)decan-9-one. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 33 (7). 666 -667 .

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chin.19...

Abstract

Degradation of the tolyl group in the tricyclic ketone 1b followed by stereospecific reduction of the resultant ketoester (6) furnishes the title compound (4) containing a new tetracyclic framework, establishing the stereochemistry of the aryl group in 1.

Item Type: Editorials/Short Communications
Additional Information: Copyright of this article belongs to National Institute of Science Communication and Information Resources.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 24 May 2011 09:05
Last Modified: 24 May 2011 09:05
URI: http://eprints.iisc.ernet.in/id/eprint/36287

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