Chandrasekhar, S and Roy, CD (1994) Conformationally Restricted Criegee Intermediates: Evidence for Formation and Stereoelectronically Controlled Fragmentation. In: Perkin transactions 2 (10). 2141 -2143 .
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1994...
Abstract
The Baeyer-Villiger reaction of 2-(2-oxocyclohexyl) acetic acid occurs via a bicyclic Criegee intermediate, which fragments with stereoelectronic control, as evidenced by product analysis; the reaction of the but-2-yl ester and of 2-(2-oxocyclopentyl) acetic acid also show evidence of such stereoelectronic control, but less convincingly.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Royal society of chemistry. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 26 Mar 2011 04:49 |
| Last Modified: | 26 Mar 2011 04:49 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/36301 |
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