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Conformationally Restricted Criegee Intermediates: Evidence for Formation and Stereoelectronically Controlled Fragmentation

Chandrasekhar, S and Roy, CD (1994) Conformationally Restricted Criegee Intermediates: Evidence for Formation and Stereoelectronically Controlled Fragmentation. In: Perkin transactions 2 (10). 2141 -2143 .

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Abstract

The Baeyer-Villiger reaction of 2-(2-oxocyclohexyl) acetic acid occurs via a bicyclic Criegee intermediate, which fragments with stereoelectronic control, as evidenced by product analysis; the reaction of the but-2-yl ester and of 2-(2-oxocyclopentyl) acetic acid also show evidence of such stereoelectronic control, but less convincingly.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal society of chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 26 Mar 2011 04:49
Last Modified: 26 Mar 2011 04:49
URI: http://eprints.iisc.ernet.in/id/eprint/36301

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