Chandrasekhar, S and Roy, CD (1994) Conformationally Restricted Criegee Intermediates: Evidence for Formation and Stereoelectronically Controlled Fragmentation. In: Perkin transactions 2 (10). 2141 -2143 .
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The Baeyer-Villiger reaction of 2-(2-oxocyclohexyl) acetic acid occurs via a bicyclic Criegee intermediate, which fragments with stereoelectronic control, as evidenced by product analysis; the reaction of the but-2-yl ester and of 2-(2-oxocyclopentyl) acetic acid also show evidence of such stereoelectronic control, but less convincingly.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Royal society of chemistry.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||26 Mar 2011 04:49|
|Last Modified:||26 Mar 2011 04:49|
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