Sanjaykumar, SR and Mukri, Bhaskar Devu and Patil, Satish and Madras, Giridhar and Hegde, MS (2011) Ce0.98Pd0.02O2-delta: Recyclable, ligand free palladium(II) catalyst for Heck reaction. In: Journal of Chemical Sciences, 123 (1). pp. 47-54.
jcs_123-1.pdf - Published Version
Palladium substituted in cerium dioxide in the form of a solid solution, Ce-0.98 Pd-0.02 O-1.98 is a new heterogeneous catalyst which exhibits high activity and 100% trans-selectivity for the Heck reactions of aryl bromides including heteroaryls with olefins. The catalytic reactions work without any ligand. Nano-crystalline Ce-0.98 Pd-0.02 O-1.98 is prepared by solution combustion method and Pd is in +2 state. The catalyst can be separated, recovered and reused without significant loss in activity.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Indian Academy of Sciences.|
|Keywords:||Ionic Pd; carbon-carbon coupling; Heck reaction; Pd-ceria; heterogeneous catalysis|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Division of Mechanical Sciences > Chemical Engineering
|Date Deposited:||29 Mar 2011 08:19|
|Last Modified:||29 Mar 2011 08:20|
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