Reddy, Venkata S and Krishnamurthy, Setharampattu S and Nethaji, Munirathinam (1994) Organometallics of diphosphazanes. Part 10. Dinuclear group 6 metal carbonyl complexes bridged by a cyclodiphosphazane in its cis or trans form. In: Dalton Transactions (18). pp. 2661-2667.
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Mononuclear Group 6 metal tetracarbonyl complexes containing a cyclodiphosphazane ligand, [PhNP(OC(6)H(4)Me-p)](2) (L), have been used as synthons to prepare homo- and hetero-bimetallic complexes in which the cyclodiphosphazane bridges the two metal centres in its cis or trans isomeric forms. The dimolybdenum complex [Mo-2(eta(5)-C5H5)(2)(CO)(4)(mu-L)] has also been synthesized. The trends in P-31 NMR chemical shifts and the structural features as revealed by X-ray crystallography are discussed.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Royal society of chemistry.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||08 Apr 2011 10:34|
|Last Modified:||08 Apr 2011 10:34|
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