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Soft-chemical synthesis of new non-linear optical materials, K0.5M0.5Ti0.5OPO4(M = Nb, Ta),related to KTiOPO4

Rangan, Kasthuri K and Prasad, Raghavendra B and Subramanian, CK and Gopalakrishnan, J (1994) Soft-chemical synthesis of new non-linear optical materials, K0.5M0.5Ti0.5OPO4(M = Nb, Ta),related to KTiOPO4. In: Journal of the Chemical Society - Series Chemical Communications (2). pp. 141-142.

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Abstract

Soft-chemical oxidation of KTiOPO4-like KM(0.5)(V)Ti(0.5)(III)OPO(4) (M = Nb, Ta) using chlorine in CHCl3 is accompanied by partial deintercalation of potassium, yielding K(0.5)MV(0.5)Ti(0.5)(IV)OPO(4) compounds which are new non-linear optical materials that exhibit efficient second-harmonic generation of 1064 nm radiation, as does KTiOPO4.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal society of chemistry.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Division of Physical & Mathematical Sciences > Physics
Date Deposited: 13 Apr 2011 10:01
Last Modified: 13 Apr 2011 10:01
URI: http://eprints.iisc.ernet.in/id/eprint/36807

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