ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Studies of phosphazenes. Part 34. group 6 metal carbonyl complexes of bis(pyrazolyl)cyclotriphosphazenes

Chandrasekaran, Annamalai and Krishnamurthy, Setharampattu S and Nethaj, Munirathinam (1994) Studies of phosphazenes. Part 34. group 6 metal carbonyl complexes of bis(pyrazolyl)cyclotriphosphazenes. In: Dalton Transactions (1). pp. 63-68.

[img] PDF
Studies_of_Phosphazenes..pdf - Published Version
Restricted to Registered users only

Download (783Kb) | Request a copy
Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1994...

Abstract

Reactions of the bis(3,5-dimethylpyrazol-1-yl)cyclotriphosphazenes gem-N3P3Ph4(C3HN2Me2)2 (L1) and N3P3(MeNCH2CH2O)2(C3HN2Me2)2 (L2) with [M(CO)6] (M = Mo or W) afford complexes of the type [M(CO)3L] (L = L1 or L2), which have been characterised by IR and NMR spectroscopic data. The structures of [Mo(CO)3L1], [W(CO)3L2] and the ligand L2 have been determined by single-crystal X-ray diffraction. The phosphazenes act as novel tridentate NNN-donor ligands with two pyrazolyl nitrogen atoms and one phosphazene ring nitrogen atom bonded to the metal atom

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal society of chemistry.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 13 Apr 2011 06:54
Last Modified: 13 Apr 2011 06:54
URI: http://eprints.iisc.ernet.in/id/eprint/36841

Actions (login required)

View Item View Item