Singh, Ram Niwas and Padma, DK (1994) Studies on pyridinium hexafluorostannate and its derivatives. In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 24 (6). pp. 963-977.Full text not available from this repository.
Pyridinium hexafluorostannate, (C5H5NH)2SnF6, has been prepared by the reaction of stannous chloride or tin metal with pyridinium poly(hydrogen fluoride), PPHF, and identified by chemical analysis, IR and NMR (H-1, F-19, C-13). Making use of (C5H5NH)2SnF6 as a precursor, the following important hexafluorostannate salts have been synthesized in high yields at room temperature by ionic exchange: M2SnF6 (M = NH4, Na, K, Rb, Cs) and BaSnF6. These salts have been characterised by chemical analysis and infrared spectroscopy. Indexed powder X-ray diffraction data for Na2SnF6, Rb2SnF6 and Cs2SnF6 have been reported.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Taylor and francis group.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||13 Apr 2011 06:33|
|Last Modified:||13 Apr 2011 06:33|
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