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A simple strategy for spirocyclopentannullation of cyclic ketones. Formal total synthesis of (+/-)-acorone

Srikrishna, Adusumili and Kumar, Praveen P and Viswajanani, Ranganathan (1996) A simple strategy for spirocyclopentannullation of cyclic ketones. Formal total synthesis of (+/-)-acorone. In: Tetrahedron Letters, 37 (10). pp. 1683-1686.

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Official URL: http://dx.doi.org/10.1016/0040-4039(96)00109-8

Abstract

A general and simple methodology for spirocyclopentannulation of cyclic ketones (or 4,4-disubstituted cyclopentenones from acyclic ketones) and its application in the synthesis of the spirodienone 7 via a prochiral precursor constituting a formal total synthesis of (+/-)-acorone (6), are described.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 21 Apr 2011 07:54
Last Modified: 21 Apr 2011 07:54
URI: http://eprints.iisc.ernet.in/id/eprint/37038

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