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Chemo- and stereoselective reduction of alpha,beta-epoxyketones with diisopropoxytitanium(III) tetrahydroborate

Ravikumar, KS and Chandrasekaran, Srinivasan (1996) Chemo- and stereoselective reduction of alpha,beta-epoxyketones with diisopropoxytitanium(III) tetrahydroborate. In: Tetrahedron, 52 (27). pp. 9137-9142.

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Official URL: http://dx.doi.org/10.1016/0040-4020(96)00465-6

Abstract

Reduction of alpha,beta-epoxyketones with diisopropoxytitanium(III) tetrahydroborate in dichloromethane under mild conditions (-78 degrees--> -20 degrees C) provides anti- (or erythro-) alpha,beta-epoxy alcohols in high yields with high degree of chemo- and stereoselectivity. Copyright (C) 1996 Elsevier Science Ltd

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 21 Apr 2011 05:33
Last Modified: 21 Apr 2011 05:33
URI: http://eprints.iisc.ernet.in/id/eprint/37069

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