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Extended Huckel molecular orbital calculations on hydroxobridged heterotrinuclear cobalt(III) complexes

Shafi, KVPM and Sathyanarayana, DN (1996) Extended Huckel molecular orbital calculations on hydroxobridged heterotrinuclear cobalt(III) complexes. In: Indian Journal of Chemistry - Section A: Inorganic, Physical, Theoretical and Analytical Chemistry, 35 (11). pp. 915-919.

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Official URL: http://www.niscair.res.in/ScienceCommunication/Res...

Abstract

EHT calculations on heterotrinuclear cobalt(III) complexes of the type [Cu{(OH)(2)Co(L(4))}(2)](4+) where L(4) denotes (en)(2) or (NH3)(4), en = ethylenediamine and their component species have been carried out. The results regarding bonding and structure for the trinuclear complexes are compared with those for the monomer components such as [Co(en)(2)(OH)(2)](+), [Co(NH3)(4)(OH)(2)](+) and [Cu(OH)(4)](2-) are discussed.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to National institute of science communication and information resources.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 26 Apr 2011 05:53
Last Modified: 26 Apr 2011 05:53
URI: http://eprints.iisc.ernet.in/id/eprint/37179

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