Raman, Sumathi and Asish K, Chandra (1992) Mechanism of ?-cleavage in the excited states of keto sulfides. In: Perkin Transactions 2 (2). pp. 291-294.
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1992...
Abstract
The beta-cleavage process in photoexcited ketones of structure RCOCH2X (X = CH2CH3, OCH3, SCH3; R = CH3, Ph) has been studied using the configuration interaction procedure within the framework of MINDO/3. The results explain qualitatively why the beta-cleavage process is faster than the alpha-cleavage process in keto sulfides while in keto ethers the reverse is true.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Royal Soc Chemistry. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 05 May 2011 06:14 |
| Last Modified: | 05 May 2011 06:14 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/37214 |
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