Chandra, A and Bagchi, B (1992) Molecular interpretation of the linear relationship between the entropy and the enthalpy of activation of charge transfer reactions in polar liquids. In: Proceedings of the Indian Academy of Sciences - Chemical Sciences, 104 (3). pp. 399-407.
Molecular_interpretation_of.pdf - Published Version
The well-known linear relationship (T?S# =??H# +?, where 1 >? > 0,? > 0) between the entropy (?S#) and the enthalpy (?H#) of activation for reactions in polar liquids is investigated by using a molecular theory. An explicit derivation of this linear relation from first principles is presented for an outersphere charge transfer reaction. The derivation offers microscopic interpretation for the quantities? and?. It has also been possible to make connection with and justify the arguments of Bell put forward many years ago.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Indian Academy of Sciences.|
|Keywords:||Molecular interpretation;linear relationship;entropy; enthaipy of activation;polar liquids;charge transfer reactions|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit|
|Date Deposited:||28 Apr 2011 05:02|
|Last Modified:||28 Apr 2011 05:02|
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