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Insertion of nickel nanoparticles in the interlayers of alpha-zirconium phosphate by the decomposition of the intercalated nickel acetate

Ayyappan, S and Rao, CNR (1996) Insertion of nickel nanoparticles in the interlayers of alpha-zirconium phosphate by the decomposition of the intercalated nickel acetate. In: European Journal of Solid State and Inorganic Chemistry, 33 (8). pp. 737-749.

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Official URL: http://www.sciencedirect.com/science/journal/09924...

Abstract

By employing EXAFS and magnetic measurements, it is shown that nanoparticles of nickel along with those of NiO are incorporated between the layers of a-zirconium phosphate (ZrP) by the thermal decomposition of nickel acetate intercalated in ZrP. The nickel nanoparticles are superparamagnetic. Hydrogen reduction produces small ferromagnetic nickel particles, most of which appear to be outside the interlayer space of ZrP.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier science.
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 29 Apr 2011 06:04
Last Modified: 29 Jun 2011 07:04
URI: http://eprints.iisc.ernet.in/id/eprint/37319

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