ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Reaction of diisopropoxytitanium(III) tetrahydroborate with selected organic compounds containing representative functional groups

Ravikumar, KS and Chandrasekaran, S (1996) Reaction of diisopropoxytitanium(III) tetrahydroborate with selected organic compounds containing representative functional groups. In: Journal of Organic Chemistry, 61 (3). pp. 826-830.

[img] PDF
Reaction_of.pdf - Published Version
Restricted to Registered users only

Download (365Kb) | Request a copy
Official URL: http://pubs.acs.org/doi/abs/10.1021/jo951313t

Abstract

Diisopropoxytitanium(III) tetrahydroborate, ((PrO)-Pr-1)(2)TiBH4), generated in situ in dichloromethane from diisopropoxytitanium dichloride and benzyltriethylammonium borohydride in a 1:2 ratio selectively reduces aldehydes, ketones, acid chlorides, carboxylic acids, and N-Boc-protected amino acids to the corresponding alcohols in excellent yield under very mild reaction conditions (-78 to 25 degrees C).

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 10 May 2011 07:33
Last Modified: 10 May 2011 07:33
URI: http://eprints.iisc.ernet.in/id/eprint/37505

Actions (login required)

View Item View Item