Hajra, JP and Lee, Hong-Kee and Frohberg, Martin G (1992) Representation of thermodynamic properties of ternary systems and its application to the system silver-gold-copper at 1350 K. In: Metallurgical and Materials Transactions B, Process Metallurgy and Materials Processing Science, 23 (6). pp. 747-752.
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The article presents a generalized analytical expression for description of the integral excess Gibbs free energy of mixing of a ternary system. Twelve constants of the equation are assessed by the least mean squares regressional analysis of the experimental integral excess data of the constituent binaries; three ternary parameters are evaluated by a regressional analysis based on the partial experimental data of a component of the ternary system. The assessed values of the ternary parameters describe the nature of the ternary interaction in the system. Activities and isoactivities of the components in the Ag-Au-Cu system at 1350 K are calculated and found to be in good agreement with the experimental data. This analytical treatment is particularly useful to ternary systems where the thermodynamic data are available from different sources.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Minerals Metals Materials Soc.|
|Department/Centre:||Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)|
|Date Deposited:||30 May 2011 09:17|
|Last Modified:||30 May 2011 09:17|
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