Srikrishna, Adusumili and Nagaraju, S and Reddy, TJ and Venkateswarlu, S (1996) Synthetic approaches to homogynolides A and B. In: Pure and Applied Chemistry, 68 (3). pp. 699-702.
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Abstract
A four step, efficient and general methodology for the conversion of a cyclic ketone into the corresponding alpha-spiro-beta-methylene-gamma-butyrolactone, the key structural feature present in tricyclic sesquiterpenes bakkanes, has been developed employing a regiospecific 5-exo dig radical cyclisation reaction as the key step. The methodology has been extended to the total synthesis of bakkanes including homogynolide-B and chiral homogynolide-A.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to International Union of Pure and Applied Chemistry. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 31 May 2011 05:10 |
| Last Modified: | 31 May 2011 05:10 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/37622 |
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