Mehta, Goverdhan and Maity, Pulakesh (2011) A total synthesis of 11-O-methyldebenzoyltashironin. In: Tetrahedron Letters, 52 (15). pp. 1749-1752.
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A concise total synthesis of 11-O-methyldebenzoyltashironin is reported in which oxidative dearomatization-IMDA-RCM triad constitutes the key ring forming steps, while an unorthodox DIBAL-H mediated stereo- and regioselective reductive epoxide openings and implementation of the vinyl bromide-carbonyl equivalency concept were pivotal to the success of this endeavor. (C) 2011 Elsevier Ltd. All rights reserved.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Keywords:||Natural products;Neurotrophic agents;Oxidative dearomatization;Intramolecular Diels-Alder reaction;Ring closing metathesis|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||20 May 2011 06:36|
|Last Modified:||20 May 2011 06:36|
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