Basu, BJ and Padma, DK and Rajagopalan, SR (1995) Enhanced sensitivity for the differential pulse polarographic determination of molybdenum(VI) based on adsorption catalytic current. In: Fresenius' Journal of Analytical Chemistry, 352 (6). pp. 598-599.
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A differential pulse polarographic (DPP) method based on the adsorption catalytic current in a medium containing chlorate and 8-hydroxyquinoline (oxine) is suggested for the determination of molybdenum(VI). Experimental conditions such as pH and the composition of supporting electrolyte have been optimized to get a linear calibration graph at trace levels of Mo(VI). The sensitivity for molybdenum can be considerably enhanced by this method. The influence of possible interferences on the catalytic current has been investigated. The sensitivity of the method is compared with those obtained for other DPP methods for molybdenum. A detection limit of 1.0 x 10(-8) mol/L has been found.
|Item Type:||Editorials/Short Communications|
|Additional Information:||Copyright of this article belongs to Springer.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||19 May 2011 04:38|
|Last Modified:||19 May 2011 11:13|
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