Mishra, AK and Bhattacharjee, B and Rangarajan, SK (1992) Theory of electron transfer processes via chemisorbed intermediates: Part II. Current-potential characteristics. In: Journal of Electroanalytical Chemistry, 331 (1-2). pp. 801-813.
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Current-potential characteristics are obtained numerically for a lone-adsorbate-mediated anodic charge transfer at the electrode-solution interface. An increase in the overpotential leads to the appearance of maxima in the anodic current-potential plots instead of the extended activationless region (i.e. a saturation current at large positive overpotentials) predicted by the direct heterogeneous outer-sphere anodic charge transfer process. A detailed analysis of the dependence of current-potential profiles and other kinetic parameters on various system parameters is also presented.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier science.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||30 May 2011 05:38|
|Last Modified:||30 May 2011 05:38|
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