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Chemistry of Tetrathiomolybdate: Aziridine Ring Opening Reactions and Facile Synthesis of Interesting Sulfur Heterocycles

Sureshkumar, Devarajulu and Koutha, Srinivasa Murthy and Chandrasekaran, Srinivasan (2005) Chemistry of Tetrathiomolybdate: Aziridine Ring Opening Reactions and Facile Synthesis of Interesting Sulfur Heterocycles. In: Journal of The American Chemical Society, 127 (37). pp. 12760-12761.

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Abstract

Benzyltriethylammonium tetrathiomolybdate, $[BnEt_3N]_2MoS_4$, has been used successfully to effect ring opening of aziridines in a regiospecific and stereospecific manner under mild reaction conditions without the use of Lewis acid catalyst. Utility of this reagent in tandem and multistep processes in a one-pot operation for the synthesis of various novel sulfur heterocycles in very good yield is also reported.

Item Type: Journal Article
Additional Information: The copyright for this article belongs to American chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 07 Oct 2005
Last Modified: 27 Aug 2008 11:30
URI: http://eprints.iisc.ernet.in/id/eprint/3790

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