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Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels

Selvakumar, Natesan and Janaki, Seenivasaga N and Pramod, Kakumanu and Rao, Subba GSR (1995) Synthesis based on cyclohexadienes. Part 17. Total synthesis of the sesquiterpenes of Eremophila georgei diels. In: Perkin Transactions 1 (7). pp. 839-846.

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Abstract

The first stereoselective total synthesis of the novel sesquiterpenes 1 and 2 is described. The preparation of the key intermediate 27 involved a rearrangement of a bicyclo[3.2.1] octane framework to an isomeric bicyclo[3.2.1]octane skeleton via a bicyclo[2.2.2]octane derivative.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 26 May 2011 08:03
Last Modified: 26 May 2011 08:03
URI: http://eprints.iisc.ernet.in/id/eprint/37947

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