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Ultraviolet photoelectron spectroscopy of the hydrogen bonded heterodimer H2Scdots, three dots, centeredHCl

Ananthavel, SP and Pradeep, T and Hegde, MS (1992) Ultraviolet photoelectron spectroscopy of the hydrogen bonded heterodimer H2Scdots, three dots, centeredHCl. In: Spectrochimica Acta Part A: Molecular Spectroscopy, 48 (11-12). pp. 1795-1799.

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Official URL: http://dx.doi.org/10.1016/0584-8539(92)80254-T

Abstract

The HeI photoelectron spectrum of the hydrogen bonded hetero-dimer H2Scdots, three dots, centeredHCl shows two vertical ionization energies at 10.91 and 12.16 eV. Ab initio MO calculations reveal that these features are due to the sulphur and chlorine lone pair ionizations respectively. Results show that while the ground ionic state is repulsive the first excited ionic state is strongly bound. The photoelectron spectrum of the diethyl sulphidecdots, three dots, centeredHCl complex is similar to that of H2Scdots, three dots, centeredHCl.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier science.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 30 May 2011 05:12
Last Modified: 30 May 2011 05:12
URI: http://eprints.iisc.ernet.in/id/eprint/37972

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