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Intramolecular Reactivity - Keto Participation in the Hydrolysis of N-Methyl-N-(9-Oxobicyclo[3.3.1]Nonan-2-Alpha-YL) Morpholinium Iodide, and A Cannizzaro-Type Reaction of 3-(2-Oxocyclohexyl)Propanal

Chandrasekhar, S and Venkatesan, V (1995) Intramolecular Reactivity - Keto Participation in the Hydrolysis of N-Methyl-N-(9-Oxobicyclo[3.3.1]Nonan-2-Alpha-YL) Morpholinium Iodide, and A Cannizzaro-Type Reaction of 3-(2-Oxocyclohexyl)Propanal. In: Journal of Chemical Research (5). pp. 170-171.

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Official URL: http://www.sciencereviews2000.co.uk/view/journal/j...

Abstract

Mechanistic studies of two intramolecular processes, nucleophilic displacement of N-methylmorpholinium in N-methyl-N-{9-oxobicyclo[3,3,1]nonan-2 alpha-yl}morpholinium iodide, anchimerically assisted by keto carbonyl, and a Cannizzaro-type reaction of 3-(2-oxocyclohexyl)propanal, occurring via axial hydride transfer onto the cyclohexanone, are reported.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Science Reviews 2000 Ltd.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 31 May 2011 06:14
Last Modified: 31 May 2011 06:14
URI: http://eprints.iisc.ernet.in/id/eprint/38035

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