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Electrical and magnetic properties of pure and Li intercalated Bi1.7-xPbxV8O16 phases

Ramakrishnan, PA and Sugantha, M and Nagarajan, T and Varadaraju, UV (1998) Electrical and magnetic properties of pure and Li intercalated Bi1.7-xPbxV8O16 phases. In: Materials Letters, 36 (1-4). 137 -141.

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Official URL: http://dx.doi.org/10.1016/S0167-577X(98)00019-6

Abstract

Hollandite oxides of the type Bi1.7-xPbxV8O16 have been synthesized. The electrical resistivity studies show that the conductivity improves upon Pb substitution. The feasibility of Li intercalation in the system has been established. Magnetic susceptibility studies on the pure and Li intercalated phases show that except for pure Bi1.7V8O16, all phases exhibit Pauli paramagnetism. No superconductivity is encountered down to 12 K in any of the phases. (C) 1998 Elsevier Science B.V. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Hollandite;Li intercalation;Pauli paramagnetism; Superconductivity;Bismuth lead vanadates.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 09 Jun 2011 07:30
Last Modified: 09 Jun 2011 07:30
URI: http://eprints.iisc.ernet.in/id/eprint/38087

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