Singh, Ram Niwas and Padma, DK (1995) Pyridinidm Hexafluorotitanate and its Derivatives. In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 25 (4). 653-662 .Full text not available from this repository.
Pyridinium hexafluorotitanate, (C5H5NH)(2)TiF6, has been prepared by the reaction of titanium metal with pyridinium poly(hydrogen fluoride), PPHF, at room temperature. Making use of (C5H5NH)(2)TiF6 as a precursor, ammonium and alkali metal hexafluorotitanates, M(2)TiF(6) (M = NH4, Na, K, Rb and Cs) have been synthesized by metathesis. These hexafluorotitanates have been characterized by chemical analyses, infrared and NMR (H-1 and F-19) spectroscopy and powder X-ray diffraction methods. Indexed powder X-ray diffraction data for Rb2TiF6 and Cs2TiF6 have been reported.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Taylor and Francis Group.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||02 Jun 2011 10:05|
|Last Modified:||02 Jun 2011 10:05|
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