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Dimethyl Sulphoxide Complexes of rare earth chlorides

Ramalingam, SK and Soundararajan, S (1967) Dimethyl Sulphoxide Complexes of rare earth chlorides. In: Zeitschrift fur anorganische und allgemeine Chemie, 353 (3-4). pp. 216-222.

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Abstract

Dimethyl sulphoxide complexes of seven rare earth chlorides of the general formula $MCl_{3 . n}$ DMSO where M La, Ce, Pr, Nd, Sm, or Gd; n = 4 and M = Y; n = 3 have been isolated and characterized. The infrared studies reveal coordination through oxygen. The conductance data in acetonitrile, dimethyl formamide and dimethyl sulphoxide suggest a coordination number of 8 for lanthanons and 7 for yttrium. A bridge-type structure involving chlorine is postulated.

Item Type: Journal Article
Additional Information: The copyright belongs to Verlag GmbH & Co. KGaA, Weinheim.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 18 Oct 2005
Last Modified: 27 Aug 2008 11:30
URI: http://eprints.iisc.ernet.in/id/eprint/3842

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