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Synthesis based on cyclohexadienes. Part-27. Synthesis of functionalized tricyclo[5.2.2.0(1,5)]undecanes

Rao, GSRS and Hariprakasha, HK and Girija, T and Bhaskar, KV (1997) Synthesis based on cyclohexadienes. Part-27. Synthesis of functionalized tricyclo[5.2.2.0(1,5)]undecanes. In: Journal of the Indian Chemical Society, 74 (11-12). pp. 961-969.

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Abstract

A new methodology for the construction of tricyclo[5.2.2.0(1,5)]undecanes is described from indane-4-carboxylic acids. Birch reduction of indane-4-carboxylic acids followed by conjugation and cycloaddition with alpha-chloroacrylonitrile and hydrolysis lead to the tricyclic compounds 36 and 48 which are intermediates in the eremolactone synthesis.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Indian Chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 23 Jun 2011 06:40
Last Modified: 23 Jun 2011 06:40
URI: http://eprints.iisc.ernet.in/id/eprint/38520

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