Prasad, Kavirayani R and Penchalaiah, Kamala (2011) Enantiodivergent total synthesis of microcarpalide from L-tartaric acid. In: Tetrahedron, 67 (23). pp. 4268-4276.
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Stereoselective approach for the synthesis of both enantiomers of bio-active decanolactone microcarpalide is described from L-tartaric acid. The synthesis of the key intermediates en route to the natural product is achieved from L-tartaric acid involving the elaboration of gamma-hydroxy amide derived from tartaric acid and ring opening of an epoxide derived from tartaric acid. (C) 2011 Elsevier Ltd. All rights reserved.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Keywords:||Decanolide;Microcarpalide;Tartaric acid;Total synthesis|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||29 Jun 2011 08:53|
|Last Modified:||21 Oct 2011 09:29|
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