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Enantiodivergent total synthesis of microcarpalide from L-tartaric acid

Prasad, Kavirayani R and Penchalaiah, Kamala (2011) Enantiodivergent total synthesis of microcarpalide from L-tartaric acid. In: Tetrahedron, 67 (23). pp. 4268-4276.

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Official URL: http://dx.doi.org/10.1016/j.tet.2011.03.102

Abstract

Stereoselective approach for the synthesis of both enantiomers of bio-active decanolactone microcarpalide is described from L-tartaric acid. The synthesis of the key intermediates en route to the natural product is achieved from L-tartaric acid involving the elaboration of gamma-hydroxy amide derived from tartaric acid and ring opening of an epoxide derived from tartaric acid. (C) 2011 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Decanolide;Microcarpalide;Tartaric acid;Total synthesis
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 29 Jun 2011 08:53
Last Modified: 21 Oct 2011 09:29
URI: http://eprints.iisc.ernet.in/id/eprint/38618

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