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Solvation dynamics of a quadrupolar solute in dipolar liquids

Sethia, Ashok and Bagchi, Biman (1999) Solvation dynamics of a quadrupolar solute in dipolar liquids. In: Journal of the Physical Society of Japan, 68 (1). 303-306 .

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Official URL: http://jpsj.ipap.jp/link?JPSJ/68/303/

Abstract

A microscopic calculation of solvation dynamics of dipolar and quadrupolar solutes in liquid water and acetonitrile is presented. The solvation is found to he biphasic. The calculated solvation time correlation function of ionic quadrupolar solute (K+) in water is in good agreement with re cent computer simulation results. Present study reveals some interesting aspects of quadrupolar solvation dynamics which differ significantly from that of ionic and dipolar solvation.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Institute of Pure and Applied Physics.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 29 Jun 2011 08:35
Last Modified: 29 Jun 2011 08:35
URI: http://eprints.iisc.ernet.in/id/eprint/38772

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