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Structure of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecyl 1,10-ditosylate by X-ray crystallography and F-19-NMR spectroscopy

De, Soma and Lokanath, NK and Sridhar, MA and Prasad, Shashidhara J and Venkatesan, K and Bhattacharya, Santanu (1999) Structure of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecyl 1,10-ditosylate by X-ray crystallography and F-19-NMR spectroscopy. In: Journal of Molecular Structure, 479 (1). 75-81 .

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Official URL: http://dx.doi.org/10.1016/S0022-2860(98)00797-2

Abstract

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecyl 1,10-ditosylate and its precursors were synthesized and characterized by H-1- and F-19-NMR spectroscopic methods and X-ray crystallography. These compounds are building blocks for the syntheses of the surfactants containing polyperfluoromethylene spacer. The molecule has extended all-trans conformation with molecular symmetry (1) over bar (C-i). There is a reasonably strong C-H ... O interaction in the crystal and there are two F ... F intermolecular contact distances less than the sum of van der Waals radii. (C) 1999 Elsevier Science B.V. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: X-ray crystallography;NMR spectroscopy;Surfactant; Polyperfluoromethylene spacer.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 30 Jun 2011 07:42
Last Modified: 30 Jun 2011 07:42
URI: http://eprints.iisc.ernet.in/id/eprint/38802

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