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Structure-reactivity correlations of excited states of perfluorinated compounds: A time resolved Raman study

Anandhi, R and Balakrishnan, G and Mohandas, P and Umapathy, S (1999) Structure-reactivity correlations of excited states of perfluorinated compounds: A time resolved Raman study. In: Laser Chemistry, 19 (1-4). pp. 343-348.

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Official URL: http://www.hindawi.com/journals/lc/1999/068497/abs...

Abstract

This paper reports the TR3 spectral studies on perfluorinated organic systems with the objective to understand the influence of perfluorination on the excited states. We have recorded the TR3 spectra and Raman excitation profiles of the triplet excited states of decafluorobenzophenone and fluoranil. It is found that the influence of perfluorination is more pronounced in the triplet excited state than the ground state and thus leads to enhanced reactivity for perfluorinated compounds through larger structural distortions.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Hindawi Publishing Corporation.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 03 Aug 2011 10:20
Last Modified: 03 Aug 2011 10:20
URI: http://eprints.iisc.ernet.in/id/eprint/38804

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