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Synthesis and structure of a novel terminal imido complex of titanium

Jagirdar, Balaji R and Murugavel, R and Schmidt, Hans-Georg (1999) Synthesis and structure of a novel terminal imido complex of titanium. In: Inorganica Chimica Acta, 292 (1). 105-107 .

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Official URL: http://dx.doi.org/10.1016/S0020-1693(99)00092-4

Abstract

The reaction of eta(5)-Cp*TiCl3 and (LiNHBu)-Bu-t in hexanes yields a novel [eta(5)-Cp*Ti(=(NBu)-Bu-t)((NHBu)-Bu-t)(2)]Li . (NH2Bu)-Bu-t complex with a terminal tert-butylimido moiety. The synthesis and X-ray structural characterization are described. (C) 1999 Elsevier Science S.A. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Crystal structures;Titanium complexes;Imido complexes;Amido complexes
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 30 Jun 2011 09:02
Last Modified: 30 Jun 2011 09:02
URI: http://eprints.iisc.ernet.in/id/eprint/38823

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