Prasad, Kavirayani R and Gutala, Phaneendra (2011) Enantioselective total synthesis of macrosphelides A and E. In: Tetrahedron, 67 (25). pp. 4514-4520.
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Enantioselective synthesis of 16-membered trilactone macrolides, macrosphelide A and E from (S)-lactic acid is described. Key features of the synthesis include the utility of a hitherto unexplored beta-ketophosphonate derived from lactic acid and Yamaguchi lactonization leading to the title compounds. (C) 2011 Elsevier Ltd. All rights reserved.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Keywords:||Total synthesis;Macrolactone;Lactic acid;Macrosphelides|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||05 Jul 2011 10:11|
|Last Modified:||05 Jul 2011 10:11|
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