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Michael addition of masked thiolates to conjugated systems in aqueous media promoted by ammonium tetrathiomolybdate

Devan, N and Sureshkumar, D and Beadham, I and Prabhu, KR and Chandrasekaran, S (2002) Michael addition of masked thiolates to conjugated systems in aqueous media promoted by ammonium tetrathiomolybdate. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 41 (10). 2112-2115 .

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Official URL: http://www.niscair.res.in/ScienceCommunication/Res...

Abstract

Thiolates generated in situ by the action of ammonium tetrathiomolybdate on alkyl halides, thiocyanates and disulfides undergo Michael addition to alpha,beta-unsaturated esters, nitriles :and ketones in water under neutral conditions.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to National Institute of Science Communication and Information Resources.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 20 Jul 2011 07:11
Last Modified: 20 Jul 2011 07:11
URI: http://eprints.iisc.ernet.in/id/eprint/39281

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