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Orthometalation in calixarenes: Synthesis and structural characterization of a novel orthopalladated calix[4]arene bisphosphite

Mahalakshmi, L and Krishnamurthy, SS and Nethaji, M (2002) Orthometalation in calixarenes: Synthesis and structural characterization of a novel orthopalladated calix[4]arene bisphosphite. In: Current Science (Bangalore), 83 (7). pp. 870-873.

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Abstract

The treatment of a symmetrically bridged p-Bu-t-calix[4] arene bisphosphite with PdCl2(NCPh)(2) yields a novel orthopalladated derivative by a C-C bond scission of a t-butyl group attached to an aryl ring. The structure of this orthopalladated calix[4]arene derivative has been established by X-ray crystallography.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 21 Jul 2011 09:09
Last Modified: 21 Jul 2011 09:09
URI: http://eprints.iisc.ernet.in/id/eprint/39330

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